MALLINCKRODT CHEMICAL INC -- PHENYLHYDRAZINE -- 6505-00N085098 
=====================  Product Identification  =====================

Product ID:PHENYLHYDRAZINE
MSDS Date:03/05/1987
FSC:6505
NIIN:00N085098
=== Responsible Party ===
Company Name:MALLINCKRODT CHEMICAL INC
Box:800
City:PARIS
State:KY
ZIP:40362
Country:US
Info Phone Num:314-539-1600
Emergency Phone Num:314-539-1600
CAGE:23104
=== Contractor Identification ===
Company Name:MALLINCKRODT CHEMICAL WORKS LTD
Address:600 DELMAR
City:POINTE CLAIRE QUE CAN H9R
CAGE:23104
Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:908-859-2151
CAGE:62910

=============  Composition/Information on Ingredients  =============

Ingred Name:HYDRAZINE, PHENYL-; (PHENYLHYDRAZINE)
CAS:100-63-0
RTECS #:MV8925000
OSHA PEL:5 PPM, S
ACGIH TLV:0.1 PPM, S

Ingred Name:SUPP DATA:NOT BREATHE VAP. AVOID CONT W/EYES, SKIN & CLTHG.
    KEEP CNTNR CLSD. USE W/ADEQ VENT KEEP AWAY FROM HEAT,(ING 3)
RTECS #:9999999ZZ

Ingred Name:ING 2:SPARKS & FLAME.
RTECS #:9999999ZZ

Ingred Name:VENT:BECAUSE IT CAN CONTROL EMISSIONS OF CONTAM AT ITS
    SOURCE, PREVENTING DISPERSION OF IT INTO GEN WORK AREA. (ING 5)
RTECS #:9999999ZZ

Ingred Name:ING 4:PLEASE REFER TO ACGIH DOCUMENT, "INDUSTRIAL VENT, A
    MANUAL OF REC PRACTICES", MOST RECENT EDITION, FOR DETAILS.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50:(ORAL,RAT) 188 MG/KG.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:POISON. CORROSIVE TO RESP
    TRACT. MAY PRDCE SORE THROAT, COUGHING, LABORED BRTHG, DIZZ, BLUISH
    SKIN, FAINTNESS. INGEST:TOXIC. MAY BE FATAL IF SWALLOWED. CORROSIVE
    TO TISSUES. MAY CAUSE VOMI TING, DIZZ, FAINTNESS & JAUNDICE. SKIN
    CONT:CORROSIVE. CONTACT DERM & SENSIT MAY OCCUR. OTHER SYMPS (EFTS
    OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INCL REDNESS, PAIN, BURNS; ABSORPTION
    CAN PRDCE TOX EFTS NOTED FOR INHAL EYE CONT:CORROSIVE. VAPS  LIQ
    ARE DESTRUCTIVE TO TISSUE. CHRONIC:CHRONIC & ACUTE EXPOS MAY PRDCE
    BLOOD EFTS, LIVER & K IDNEY DMG. MUTAGEN REFERENCES CITED; ANIMAL
    REPRO EFT CITED; TUMORIGENIC EFTS CITED.
Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN
    DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY
    FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.

=======================  First Aid Measures  =======================

First Aid:UPON POIS BY PHENYLHYDRAZINE, SPECIFIC FIRST AID & TREATMENT
    ARE ESSNTL. GET IMMED MED ATTN FOR ANY EXPOS. INHAL:REMOVE TO FRESH
    AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG.
    CALL M D. INGEST:CALL MD IMMED. SKIN:IMMED FLUSH W/PLENTY OF WATER
    FOR AT LST 15 MINS WHILE REMOVING CONTAM CLTHG & SHOES. WASH CLTHG
    BEFORE REUSE. CALL MD IMMED. EYE:WASH W/PLENTY OF WATER FOR AT
    (SUPDAT)

=====================  Fire Fighting Measures  =====================

Flash Point:190F,88C
Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE. WATER MAY BE
    INEFFECTIVE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. ABOVE FLASH POINT,
    EXPLOSIVE VAPOR-AIR MIXTURES MAY BE FORMED.

==================  Accidental Release Measures  ==================

Spill Release Procedures:VENT AREA OF LEAK/SPILL. REMOVE ALL SOURCES OF
    IGNIT. CLEAN-UP PERS REQ PROT CLTHG & NIOSH APPRVD RESP PROT FROM
    VAPS. CNTN & RECOVER LIQ WHEN POSS. COLLECT AS HAZ WASTE & ATOMIZE
    IN SUITABLE RCRA APP RVD COMBUST CHAMBER/ABSORB W/VERMICULITE,
    (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:PROT AGAINST PHYSICAL DMG.
    OUTSIDE/DETACHED STOR IS PREF. INSIDE STOR SHOULD BE IN STD FLAMM
    LIQS STOR ROOM/CABINET. SEPARATE FROM OXIDIZING MATLS.
Other Precautions:STOR & USE AREAS SHOULD BE NO SMOKING AREAS. DO NOT
    STORE ON WOODEN FLOORS. DANGER! MAY BE FATAL IF SWALLOWED,
    INHALED/ABSORBED THRU SKIN. CORR. CAUSES BURNS. COMBUST. VAP & LIQ
    ARE EXTREMELY TOX & CO RR. CHRONIC EXPOS MAY AFFECT (SUPP DATA)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF TLV IS EXCEEDED, WEAR A NIOSH APPROVED
    SUPPLIED AIR, FULL-FACEPIECE RESPIRATOR, AIRLINED HOOD OR SELF
    CONTAINED BREATHING APPARATUS.
Ventilation:SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS
    BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS GENRLY PREF (ING 4)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT)
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
    SHOWER . WEAR IMPERVIOUS PROT CLTHG, INCL BOOTS, LAB COAT, APRON/
    (SUPDAT)
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. CONTACT LENSES
    SHOULD NOT BE WORN WHEN WORKING W/THIS MATERIAL.
Supplemental Safety and Health
FIRST AID PROC:LST 15 MINS, LIFTING LOWER & UPPER LIDS OCCAS. GET MED
    ATTN IMMED. SPILL PROC:DRY SAND, EARTH/SIMILAR MATL FOR DISP AS HAZ
    WASTE IN RCRA APPRVD FACILITY. DO NOT FLUSH TO SEWER! EYE PROT :&
    FULL LGTH FSHLD . OTHER PROT EQUIP:COVERALLS TO PVNT SKIN CONT.
    OTHER PREC:BLOOD, LIVER & KIDNEYS. DO (ING 2)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:470F,243C
Melt/Freeze Pt:M.P/F.P Text:66.0F,18.9C
Decomp Temp:Decomp Text:470F,243C
Vapor Pres:1 @ 71.8C
Vapor Density:3.7
Spec Gravity:1.099
Solubility in Water:SLIGHTLY SOLUBLE
Appearance and Odor:YELLOW CRYSTALS OR OIL; FAINT AROMATIC ODOR.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE &
    STORAGE.
Hazardous Decomposition Products:MAY FORM CARBON OXIDES & NITROGEN
    OXIDES WHEN HEATED TO DECOMPOSITION.

====================  Disposal Considerations  ====================

Waste Disposal Methods:ENSURE COMPLIANCE W/LOCAL, STATE & FEDERAL
    REGULATIONS.

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